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#1
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Foma Reversal film in 120?
"____" wrote in message ... Back when I was doing a bit of film testing and article writing for View Camera Magazine the folks at Foma sent me test rolls of the Fomapan R film for review. For reasons I can't go back to for loss of the info I found that processing the film myself was not an option. Something about the process did not appeal to me or was rather nasty. I looked at two labs, one was DK-17? in California that wanted a vast sum per roll. The other was Duggal in NYC. Duggal processed the film and it was beautiful. Not sure if they still offer the service or are in business. Unfortunately Steve Simmons and his Buddy Tim lost my film in their haste to split View camera and Camera Arts Magazines. My article was never published related to the Fomapan Films. I do however have a scan or two from the Fomapan and one roll of the reversal film. Snipping here... I wonder what the problem was with the reversal process? Were you using a chemical reversal that used something nasty? Typical color reversal processes use borains and other chemical reversal agents. Simple B&W reversal is not too difficult to do but requires some experimentation. The first developer is rather high contrast compared to the ususal negative developer. That is because most reversal is done to obtain transparencies for direct viewing or projection and the contrast of the final reversed image is controlled by the first developer. Because of the high contrast there is very little room for error in exposure or development. The first development is the only one that is critical, the remaining steps are all done to completion. As you probably know the emulsion of film contains silver halide particles having a wide range of sensitivity to light. If all the particles had the same sensitivity the film would be unable to record continuous tone subjects. In fact, the distribution of sensitivity is what differentiates low and high contrast media. In pictorial film there are some halide particals that have such low sensitity that no practical amount of exposure to light will make them developable. These will remain in the film after development and cause veiling when the film is reversed. Early attemps at reversal required very high exposure levels, that is a serious reduction of film speed, in order to obtain anything like a good revesed image. It was discovered that these very fine grain particles could be eliminated by the use of a mild halide solvent in the first developer. If the amount of solvent is chosen correctly the film speed for reversal is not much different than its speed as a negative and the reversed images will have clear highlights. A number of solvents have been used. The most common ones are thiosulfate (hypo) and in more advanced formulas thiocyanate, which is a more powerful solvent with less effects on fogging. The amount of solvent is dependant on the nature of the emulsion so no single formula will be optimum for all films. The first developer is a highly active, medium high contrast formula. Typical reversal formulas resemble developers like Kodak D-19 with the addition of the solvent. Some are even higher contrast and may contain some hydroxide to accelerate development. Actually a good print developer like Dektol will work. The next step is bleaching. The usual bleach uses either dichomate or permanganate as the bleach. These remove the metallic silver from the first development but leave the remaining halide. Dichromate bleach is the better of the two but permanganate is often used because its somewhat safer. Both require the use of sulfuric acid. After bleaching the film is usually treated in a clearing solution to remove stains left by the bleach. This is usually just a sulfite or bisulfite bath. The next step is to make the remaining halide developable. If a silver generating developer is used a the halide must be made developable by either re-exposing it to strong light or treating it in a chemical fogging agent. If a sulfide redeveloper is used the flashing or fogging step is not required. Redvelopment or second development is done in a high activity developer like Dektol or in a sulfiding solution. When sulfide is used the result is a sepia image and only washing is needed to complete the process, and, as mentioned above, the fogging step is not required. When a silver generating developer is used a final fixing step is necessary because some very insensitive halide particals will have survived both the solvent in the first developer and the re-exposure and must be removed. After the fixing step the film is washed and the process is complete. That's it. I suspect the use of the dichromate or permanganate bleach may have been the problem mentioned by the original poster. Dichromate bleach used to be available off the shelf as tray cleaner and is used in a number of alternative printing processes. It must be handled with care both because of the strong acid in the bleach and because dichromate is a suspected carcinogen. This makes both hard to obtain these days. Typical formua for reversal first developers contain anywhere from about 5 grams per liter to 15 grams per liter of thiocyanate but some contain as little as 2 grams per liter. The only way to determine the optimum amount is to experiment. -- --- Richard Knoppow Los Angeles, CA, USA |
#2
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Foma Reversal film in 120?
Richard Knoppow wrote:
Typical formua for reversal first developers contain anywhere from about 5 grams per liter to 15 grams per liter of thiocyanate but some contain as little as 2 grams per liter. The only way to determine the optimum amount is to experiment. _____ Richard, I have several reversal formulas in my files. They look very similar in terms of overall procedure. If you like, i can dig them out and put them on this forum. Many years ago i prepared an article on the subject of making 35 mm B&W slides for Peterson Photographic magazine. I never got around to sending them the sample slide and text. The test slides are still in my archives. I used Kodak's Panatomic-X which, as we all know, is no longer available. The results were very good if i recall. I have never tried to make 120 format slides. In my case they would be 6x7 cm format from my Pentax 6x7. / John -- Regards / JCH |
#3
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Foma Reversal film in 120?
"jch" wrote in message news:BFKpk.190218$gc5.62112@pd7urf2no... Richard Knoppow wrote: Typical formua for reversal first developers contain anywhere from about 5 grams per liter to 15 grams per liter of thiocyanate but some contain as little as 2 grams per liter. The only way to determine the optimum amount is to experiment. _____ Richard, I have several reversal formulas in my files. They look very similar in terms of overall procedure. If you like, i can dig them out and put them on this forum. Many years ago i prepared an article on the subject of making 35 mm B&W slides for Peterson Photographic magazine. I never got around to sending them the sample slide and text. The test slides are still in my archives. I used Kodak's Panatomic-X which, as we all know, is no longer available. The results were very good if i recall. I have never tried to make 120 format slides. In my case they would be 6x7 cm format from my Pentax 6x7. / John -- Regards / JCH I wouldn't mind having them although I suspect I may already have some. Kodak has some current formulas for reversing its motion picture film. I think I have those on this computer somewhere. Reversal of B&W was very common before video tape drove film off the market for home movies and some industrials. Processing was no mystery. I have never found definite information about the differences between ordinary negative emulsions and those intended especially for reversal but think it may have been partially the distribution of halide particle sizes to insure enough fine grain particals to insure sufficient density in the shadows of the reversed image and likely also some extra hardening to withstand the more than usually high pH developers and highly acid bleach. Color reversal is not quite the same because the silver image from the first development does not have to be bleached out until a final bleaching step at the end which removes all the metallic silver leaving only the dye image behind. -- --- Richard Knoppow Los Angeles, CA, USA |
#4
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Foma Reversal film in 120?
Richard Knoppow wrote:
I wouldn't mind having them although I suspect I may already have some. _____ R, Will dig through my notes and such in the next few days, and post what i find. Have done both B&W and colour reversal films (Agfa, Ektachrome, GAF) years ago. Pretty simple really. The colour films need constant temps, but that is easy to achieve. / John -- Regards / JCH |
#5
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Foma Reversal film in 120?
In article ,
"Richard Knoppow" wrote: I wonder what the problem was with the reversal process? I want o say it required Formulin, and I did not have it. Coupled with producing results for a job I intended to be paid for and a limited amount of practice material swayed me towards having someone else to blame Never the less I see Duggal is still in business, where the Dr15? lab is nowhere to be found. -- Reality is a picture perfected and never looking back. |
#6
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Foma Reversal film in 120?
"____" wrote in message ... In article , "Richard Knoppow" wrote: I wonder what the problem was with the reversal process? I want o say it required Formulin, and I did not have it. Coupled with producing results for a job I intended to be paid for and a limited amount of practice material swayed me towards having someone else to blame Never the less I see Duggal is still in business, where the Dr15? lab is nowhere to be found. Formalin or formaldehyde was used as a pre-hardener. It maintains its hardening in alkaline solutions like developer. Because the first developer in reversal processing is often strongly alkaline it may soften the emulsion too much. This was much more likely with film of the past than modern film, which has much harder emulsions. Formaldehyde was also commonly used in color processing as a final rinse both as a hardener and as a stabilizer for the dye. Indeed it is nasty stuff. -- --- Richard Knoppow Los Angeles, CA, USA |
#7
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Foma Reversal film in 120?
"Richard Knoppow" wrote
Formalin or formaldehyde was used as a pre-hardener. It maintains its hardening in alkaline solutions like [strongly alkaline] developer Is that the sole reason for the inclusion of paraformaldehyde in lith film developers? Can it be safely excluded if one is willing to handle the film gently. -- Nicholas O. Lindan, Cleveland, Ohio Darkroom Automation: F-Stop Timers, Enlarging Meters http://www.darkroomautomation.com/da-main.htm n o lindan at ix dot netcom dot com |
#8
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Foma Reversal film in 120?
Nicholas O. Lindan wrote:
"Richard Knoppow" wrote Formalin or formaldehyde was used as a pre-hardener. It maintains its hardening in alkaline solutions like [strongly alkaline] developer Is that the sole reason for the inclusion of paraformaldehyde in lith film developers? No. The paraformaldehyde is there to buffer the sulfite so the solution has a very low effective concentration, but reserve capacity to manage oxidation. Lith developers work by infectious development, and the higher the sulfite concentration, the worse they work. Can it be safely excluded if one is willing to handle the film gently. As long as you are not relying on infectious development. If you are serious about line work, or half-tone work, I recommend developers with paraformaldehyde, acetone, or some such, in their formulae. -- .~. Jean-David Beyer Registered Linux User 85642. /V\ PGP-Key: 9A2FC99A Registered Machine 241939. /( )\ Shrewsbury, New Jersey http://counter.li.org ^^-^^ 05:50:01 up 12 days, 11:56, 4 users, load average: 4.67, 4.79, 4.33 |
#9
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Foma Reversal film in 120?
Hello,
I would certainly be interested in developing Efke 25 4x5 as a positive. Then I could print to get the effect that I would normally get only on a 4x5 neg. It would save me a lot of time because I wouldn't have to make a film copy of the neg and then printing the resultant positive to get back the image that I have on the negative. Save me a step and a lot of work. Cheers, Bogdan jch wrote: Richard Knoppow wrote: I wouldn't mind having them although I suspect I may already have some. _____ R, Will dig through my notes and such in the next few days, and post what i find. Have done both B&W and colour reversal films (Agfa, Ektachrome, GAF) years ago. Pretty simple really. The colour films need constant temps, but that is easy to achieve. / John -- __________________________________________________ ______________ Bogdan Karasek Montréal, Québec bogdan(at)bogdanphoto.com Canada www.bogdanphoto.com "I bear witness" __________________________________________________ ______________ |
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